D. Mercurio et al., Investigations of the "tungsten-bronze"-type (Ba1-alpha Sr alpha)(6-x)La8+2x/3Ti18O54 (0 <= x <= 3) solid solutions, J EUR CERAM, 21(15), 2001, pp. 2713-2716
A study of the Ba/La/Sr ordering in the (Ba1-alphaSralpha)(6-x)La8+2x,3Ti18
O54 (0 less than or equal tox less than or equal to3) solid solutions was c
arried out by X-ray diffractometry and dielectric measurements. The maximum
of substitution is obtained for x=0 and alpha =0.33, i.e. for Ba4Sr2La8Ti1
8O54 composition. The crystal structure is closely related to the tungsten-
bronze-type structure with 3 x 3 octahedral units of perovskite columns (or
thorhombic symmetry, s.g. Pnma, a approximate to 22.4 Angstrom, b approxima
te to7.7 Angstrom, c approximate to 12.2 Angstrom). The A2 sites (pentagona
l channels) and the Al sites (rhombic channels within the perovskite-like c
olumns) are occupied by Ba and La respectively. Sr always occupies the part
icular rhombic Al' sites located at the junction of two perovskite-like col
umns which can also accept excess Ba and La. The A2 and Al' sites may be ca
tion deficient. The structure of Ba-4(Sr2La6)Ti18O54 with structural compos
ition A2(4)(Al'Al-2(8))Ti18O54, is fully ordered. The thermal behaviour of
the permittivity and, for some compositions, the occurrence of a strong dis
persion in a wide temperature range, would likely be connected both to a ca
tionic disorder (Sr, Ba and/or La) and vacancies in the rhombic Al' sites.
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