Prediction of binary azeotropic temperatures by use of topological and thermodynamic conditions for combinations of azeotropes in ternary systems

Authors
Matsuyama, H Nakamura, Y Tateno, S Takeda, K Tsuge, Y
Citation
H. Matsuyama et al., Prediction of binary azeotropic temperatures by use of topological and thermodynamic conditions for combinations of azeotropes in ternary systems, KAG KOG RON, 27(4), 2001, pp. 493-496
Citations number
8
Categorie Soggetti
Chemical Engineering
Journal title
KAGAKU KOGAKU RONBUNSHU
ISSN journal
0386216X → ACNP
Volume
27
Issue
4
Year of publication
2001
Pages
493 - 496
Database
ISI
SICI code
0386-216X(200107)27:4<493:POBATB>2.0.ZU;2-S
Abstract
A method is proposed for predicting the existence of binary azeotropes and their boiling temperatures by use of topological and thermodynamic conditio ns for combinations of azeotropes in ternary systems. The method can not on ly predict boiling temperatures but also give their confidence intervals. I ts usefulness is demonstrated by predicting azeotropic temperatures of 8 bi nary systems utilizing 559 sets of ternary azeotropic data.