Multiply bonded dimolybdenum cation immobilized in mesoporous silica: XAFSanalysis and catalytic activity in cyclopentadiene polymerization

Authors
Pillinger, M Goncalves, IS Ferreira, P Rocha, J Schafer, M Schon, D Nuyken, O Kuhn, FR
Citation
M. Pillinger et al., Multiply bonded dimolybdenum cation immobilized in mesoporous silica: XAFSanalysis and catalytic activity in cyclopentadiene polymerization, MACRO RAPID, 22(16), 2001, pp. 1302-1305
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
22
Issue
16
Year of publication
2001
Pages
1302 - 1305
Database
ISI
SICI code
1022-1336(20011107)22:16<1302:MBDCII>2.0.ZU;2-E
Abstract
MCM-41 derivatized with the cis-[Mo-2(mu -O2CMe)(2)(MeCN)(6)](2+) cation ha s been characterized by means of XAFS spectroscopy and shown to be active a s an. initiator for the cationic polymerization of methylcyclopentadiene. T he Mo-Mo quadruple bond is not disrupted during the fixation on the surface .