Solvent effects on the solvolyses of N-benzoyl-arenesulfonimidoyl chlorides

Authors
Kutuk, H Tillett, JG
Citation
H. Kutuk et Jg. Tillett, Solvent effects on the solvolyses of N-benzoyl-arenesulfonimidoyl chlorides, PHOSPHOR SU, 175, 2001, pp. 35-47
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
175
Year of publication
2001
Pages
35 - 47
Database
ISI
SICI code
1042-6507(2001)175:<35:SEOTSO>2.0.ZU;2-A
Abstract
Rates of solvolyses of N-benzoyl-arenesulfonimidoyl chlorides have been stu died in different compositions of aqueous organic solvents and analysed in terms of the mol fraction of organic solvent, the dielectric constant, the Kirk-wood function, the polarisibility, Some E-T(N) values, a multiparamete r equation and the Grunwald-Winstein equation. All these criteria were cons istent with a concerted bimolecular S-N(2) mechanism of solvolysis.