Synthesis and spectroscopic [IR, NMR (H-1, C-13, Si-29)] characterization of methylsilyl N-arylsalicylaldiminates

Authors
Goyal, M Mishra, S Singh, A
Citation
M. Goyal et al., Synthesis and spectroscopic [IR, NMR (H-1, C-13, Si-29)] characterization of methylsilyl N-arylsalicylaldiminates, PHOSPHOR SU, 175, 2001, pp. 143-152
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
175
Year of publication
2001
Pages
143 - 152
Database
ISI
SICI code
1042-6507(2001)175:<143:SAS[N(>2.0.ZU;2-I
Abstract
Reactions of MeSiCl3 in 1:1, 1:2, and 1:3 molar ratios with HOC6H4CH=NAr (A r = C6H3Me2-2,6; C6H2Me3-2,4,6; and C6H3Et2-2,6) in the presence of Et3N or C5H5N as a base afford compounds of the type MeSiCl3-x(OC6H4CH=NAr)(x) (x = 1, 2, and 3). Characterization of all these species have been carried out by elemental analysis, molecular weight determinations, and spectroscopic [IR, NMR (H-1, C-13 and Si-29)] studies.