CdSe/ZnSe quantum structures grown on GaAs(001) by molecular-beam epitaxy w
ere systematically investigated by high-resolution x-ray diffraction and hi
gh-resolution transmission-electron microscopy. Half of the initial Cd depo
sit redesorbs when migration-enhanced epitaxy is used instead of convention
al molecular-beam epitaxy for the overgrowth of the CdSe by ZnSe. This resu
lt is explained by a segregation model accounting for an enhanced redesorpt
ion of Cd due to Cd segregation and replacement of Cd by Zn in the topmost
surface layers. The observed intermixing of CdSe/ZnSe can be explained by t
his model.