An analysis of the time evolution of the response of diamond particle detec
tors is carried out, using as a probe 5.5 MeV alpha particles impinging on
high-quality diamond films grown by microwave chemical vapor deposition (CV
D). Both the amplitude and the time evolution of the pulses are shown to ch
ange drastically when the detector is preirradiated with beta particles (pu
mping), a slow component developing after pumping, indicating carriers trap
ping and releasing (detrapping). Pulse shapes obtained for positive and neg
ative detector polarities are compared in both the as-grown and pumped stat
es. The presence of at least two trapping centers for holes is necessary to
explain the results, the shallower having an activation energy of about 0.
3 eV. The effects of pumping are clarified, and the different role played b
y electrons and holes is evidenced. We modify a previous model for trapping
-detrapping behavior originally applied to Si(Li) detectors to describe the
more complex behavior of CVD diamond detectors, and develop a computer sim
ulation based on it. The simulated pulse shapes agree very well with experi
ment with reasonable values of the physical parameters involved, making thi
s technique helpful for studying and identifying defects which are responsi
ble for limitation of the efficiency of CVD diamond particle detectors. Fie
ld-assisted detrapping seems to take place for fields of about 10(4) V/cm.