Pe. Kornilovitch et Am. Bratkovsky, Orientational dependence of current through molecular films - art. no. 195413, PHYS REV B, 6419(19), 2001, pp. 5413
We study the current through molecular films as a function of the orientati
on of the molecules in the film with respect to electrodes. It may change b
y more than an order of magnitude, depending on the angle between the axis
of the molecules and the normal to the electrode. This is a consequence of
a strong directional character of p orbitals that determine the conductance
through the conjugated molecules. We demonstrate this result on an exactly
solvable model, and present the calculations for two different experimenta
lly accessible molecular films sandwiched between gold electrodes.