Synthesis, crystal structure, spectroscopic data and magnetic properties of the bis(imidazole-4-acetato)copper(II) complex

Authors
Drozdzewski, P Pawlak, B Glowiak, T
Citation
P. Drozdzewski et al., Synthesis, crystal structure, spectroscopic data and magnetic properties of the bis(imidazole-4-acetato)copper(II) complex, POL J CHEM, 75(11), 2001, pp. 1711-1718
Citations number
27
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
75
Issue
11
Year of publication
2001
Pages
1711 - 1718
Database
ISI
SICI code
0137-5083(200111)75:11<1711:SCSSDA>2.0.ZU;2-I
Abstract
A novel complex of copper(III) and imidazole-4-acetic acid has been crystal lized and investigated by X-ray diffraction, magnetic and spectroscopic (IR , Raman, UV-Vis) methods. The complex of formula [Cu(ia)(2)] has crystallog raphic Pbca symmetry. The copper(II) ion is situated in the symmetry centre and chelated by two ligand molecules via the oxygen and one of the imidazo le ring nitrogen atoms. The compound shows a magnetic moment of 2.03 BM.