A novel saddle-form macrocyclic barium complex-synthesis, characterization, mechanism and X-ray crystal structure

Authors
Pan, ZQ Luo, QH Duan, CY Shen, MC
Citation
Zq. Pan et al., A novel saddle-form macrocyclic barium complex-synthesis, characterization, mechanism and X-ray crystal structure, POLYHEDRON, 20(24-25), 2001, pp. 2945-2950
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
20
Issue
24-25
Year of publication
2001
Pages
2945 - 2950
Database
ISI
SICI code
0277-5387(20011115)20:24-25<2945:ANSMBC>2.0.ZU;2-Q
Abstract
A novel saddle-form macrocyclic barium complex was synthesized by cyclo-con densation of diformylpyridine with [BaL1(ClO4)(2)]. 3H(2)O. In the complex crystal [BaL2(ClO4)(2)(H2O)]. MeOH .1.5H(2)O, two perchlorate anions are ci s-coordinated to barium(II), and the coordinated water molecule is located on the opposite side to the perchlorate anion, H-1 NMR and ES MS spectra we re used to characterize its structure in methanol solution. The mechanism o f the reaction was discussed. (C) 2001 Published by Elsevier Science Ltd.