The complexity in design of components used in advanced aerospace and autom
otive applications is continuously increasing. This has led to the developm
ent of near-net shape manufacturing techniques such as laser engineered net
-shaping (LENS (TM)) which falls in the class of direct laser deposition pr
ocesses-from powder feedstock. Despite considerable advances in process opt
imization, there is a rather limited understanding of the role of metallurg
ical factors in laser deposition of alloys. This paper discusses the signif
icant role played by the thermodynamic enthalpy of mixing in the deposition
of alloys from elemental powder blends using LENS (TM). This factor influe
nces the homogeneity as well as the rate of solidification of the alloy and
consequently the microstructure and properties of the deposit. The enthalp
y of mixing could also serve as a very useful guideline in the design of no
vel alloys that are laser deposited from elemental powder blends. (C) 2001
Published by Elsevier Science Ltd. on behalf of Acta Materialia Inc.