New methods for the synthesis of P-chirogenic diphosphines: An applicationto the development of an improved asymmetric variation of the Rh(I)catalyzed [4+2] cycloaddition

Authors
Heath, H Wolfe, B Livinghouse, T Bae, SK
Citation
H. Heath et al., New methods for the synthesis of P-chirogenic diphosphines: An applicationto the development of an improved asymmetric variation of the Rh(I)catalyzed [4+2] cycloaddition, SYNTHESIS-S, (15), 2001, pp. 2341-2347
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
15
Year of publication
2001
Pages
2341 - 2347
Database
ISI
SICI code
0039-7881(200111):15<2341:NMFTSO>2.0.ZU;2-B
Abstract
A series of new P-chirogenic diphosphines has been prepared by efficient an d complementary synthetic procedures. The utilization of a series of these bidentate ligands possessing steric linker variations and a conserved P-chi rogenic domain in an asymmetric variation of the Rh(I)-catalyzed [4 + 2] en ediene cycloaddition is described.