Diastereoselective synthesis and reactions of diorganozinc reagents obtained after hydroborations with 9-BBN-H, thexylborane and catecholborane

Authors
Hupe, E Calaza, MI Knochel, P
Citation
E. Hupe et al., Diastereoselective synthesis and reactions of diorganozinc reagents obtained after hydroborations with 9-BBN-H, thexylborane and catecholborane, TETRAHEDR L, 42(50), 2001, pp. 8829-8831
Citations number
20
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
50
Year of publication
2001
Pages
8829 - 8831
Database
ISI
SICI code
0040-4039(200112)42:50<8829:DSAROD>2.0.ZU;2-X
Abstract
The scope of organoboranes, can be greatly enhanced by a boron-zinc exchang e reaction, providing organozincs that react with a broad range of electrop hiles. Diastereomerically enriched diorganozincs. can be obtained after hyd roborations with 9-BBN-H, thexylborane and catecholborane. (C) 2001 Elsevie r Science Ltd. All rights reserved.