THE MAGNETIC-PROPERTIES OF TRINUCLEAR FE(III) SUBSTITUTED CARBOXYLATECLUSTERS

Authors
TURTA KI SOLONENCO AO BULGAK II JOVMIR FK ROSENBERG M STELMASZYK P FILOTI G
Citation
Ki. Turta et al., THE MAGNETIC-PROPERTIES OF TRINUCLEAR FE(III) SUBSTITUTED CARBOXYLATECLUSTERS, Journal of radioanalytical and nuclear chemistry, 190(2), 1995, pp. 347-355
Citations number
20
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
190
Issue
2
Year of publication
1995
Pages
347 - 355
Database
ISI
SICI code
0236-5731(1995)190:2<347:TMOTFS>2.0.ZU;2-O
Abstract
The new Fe(III) complexes with isosceles or equilateral configurations showed atypical magnetic behaviour with a magnetic susceptibility whi ch does not obey the Curie-Weiss law. The experimental data were fitte d by using the Heisenberg-Dirac-van Vleck model with a spin Hamiltonia n containing different exchange parameters in the case of isosceles co nfiguration. A more elaborate Hamiltonian, taking into account the per turbation arising from a biquadratic exchange interaction was used in the case of equilateral configurations.