This work deals with the low-temperature preparation of optically active si
lica-based materials. Tb3+-doped silica monolithic gels were elaborated at
40 degreesC. Tb3+-SSA-doped SiO2-TiO2 thin films were deposited by an origi
nal sol-gel approach, the aerosol-gel process, and heat-treated at 150 degr
eesC. Organic complexation of terbium ions was used to improve the active p
roperties of doped silica gels and thin-film samples. Spectroscopic charact
erisations are reported for these samples. Photoluminescence increase by a
factor two was observed for complexation by sulphosalicylic acid.