Hydrophobic ionic liquids incorporating N-alkylisoquinolinium cations and their utilization in liquid-liquid separations

Authors
Visser, AE Holbrey, JD Rogers, RD
Citation
Ae. Visser et al., Hydrophobic ionic liquids incorporating N-alkylisoquinolinium cations and their utilization in liquid-liquid separations, CHEM COMMUN, (23), 2001, pp. 2484-2485
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
2001
Pages
2484 - 2485
Database
ISI
SICI code
1359-7345(2001):23<2484:HILINC>2.0.ZU;2-H
Abstract
The first examples of Room Temperature Ionic Liquids (RTIL) containing fuse d polycyclic N-alkylisoquinolinium cations ([C(n)isoq](+)) in combination w ith the bis(perfluoroethylsulfonyl) imide anion ([BETI](-)) have been synth esized, characterized, and utilized in liquid-liquid partitioning from wate r; these salts have unexpectedly low melting points and give high distribut ion ratios for aromatic solutes, especially chlorobenzenes, between the RTI L and water.