An improved polynomial approach to the exact perturbative evaluation of low-frequency dynamic polarizabilities for a ground-state hydrogen atom

Citation
G. Figari et V. Magnasco, An improved polynomial approach to the exact perturbative evaluation of low-frequency dynamic polarizabilities for a ground-state hydrogen atom, CHEM P LETT, 348(5-6), 2001, pp. 454-460
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
348
Issue
5-6
Year of publication
2001
Pages
454 - 460
Database
ISI
SICI code
0009-2614(20011116)348:5-6<454:AIPATT>2.0.ZU;2-C
Abstract
A recently proposed exact power expansion for the dynamic (frequency-depend ent) multipole polarizabilities of a ground-state hydrogen atom has been im proved keeping its simple polynomial structure substantially unaffected and enlarging its range of convergence. The improvement is performed by adding unexpanded frequency terms taken from the formal expression of the polariz ability as a sum-over-states and subtracting their corresponding power expa nsions. The enlarged range of convergence obtained in this way covers all r eal frequencies of physical importance and the related imaginary frequencie s. (C) 2001 Elsevier Science B.V. All rights reserved.