SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF THE COMPLEX ZN(PHEN)(S2COC4H9-I)(2)

Authors
GLINSKAYA LA LEONOVA TG KIRICHENKO VN KLEVTSOVA RF LARIONOV SV
Citation
La. Glinskaya et al., SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF THE COMPLEX ZN(PHEN)(S2COC4H9-I)(2), Journal of structural chemistry, 38(1), 1997, pp. 116-120
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
38
Issue
1
Year of publication
1997
Pages
116 - 120
Database
ISI
SICI code
0022-4766(1997)38:1<116:SACAMO>2.0.ZU;2-U
Abstract
A mixed-ligand complex Zn(Phen)(S2COC4H9-i)(2) was synthesized. The si ngle crystals of the complex were studied by X-ray diffractometry. The crystals are orthorhombic, a = 20.053(2), b = 19.272(2), c = 13.203(1 ) Angstrom, V-cell = 5102.5(8) Angstrom(3), space group Pcab, Z = 8, d (calc) = 1.416 g/cm(3), R = 0.059. The structure consists of monomeric molecules in which the coordination polyhedron of the central Zn atom is a distorted octahedron (CN = 6). An analysis of molecular packing and intermolecular distances showed that the molecules related by the symmetry center are involved in pronounced intermolecular interactions .