A new superhard phase, cubic BC2N, has very recently been synthesized by di
rect conversion of graphite-like BN-C solid solutions at 25 GPa and 2100 K.
The hardness. Young's modulus, fracture toughness and structure of this ph
ase have been examined using micro- and nanoindentation and transmission el
ectron microscopy. The hardness and elastic modulus values (E, G) of the c-
BC2N are intermediate between diamond and cubic boron nitride. which makes
this new phase the hardest known solid after diamond. (C) 2001 Elsevier Sci
ence B.V. All rights reserved.