Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

Authors
Sekiya, A Quan, HD Tamura, M Gao, RX Muratab, J
Citation
A. Sekiya et al., Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride, J FLUORINE, 112(1), 2001, pp. 145-148
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
112
Issue
1
Year of publication
2001
Pages
145 - 148
Database
ISI
SICI code
0022-1139(20011128)112:1<145:FOCUCS>2.0.ZU;2-N
Abstract
Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hyd rogen fluoride (AHF) was investigated in the presence of metal fluorides su pported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-m ethoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed. (C) 2001 Elsevier Science B.V. All rights reserved.