Electroreduction of tetrachlorosilane was carried out to fabricate silicon
(Si) nanoparticles for the first time. Typical size of the obtained particl
es is 3 nm. The transmission electron microscopy (TEM) and the electron dif
fraction pattern of the particles revealed that each particle consists only
of an amorphous phase. Optical absorption at 5.1 eV and visible photolumin
escence (PL) around 2.74 eV were observed for the particles at room tempera
ture. (C) 2001 Elsevier Science B.V. All rights reserved.