Effective medium approximation of Taylor transport in systems with static disorder

Citation
Mo. Vlad et al., Effective medium approximation of Taylor transport in systems with static disorder, J PHYS CH B, 105(47), 2001, pp. 11710-11718
Citations number
37
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
105
Issue
47
Year of publication
2001
Pages
11710 - 11718
Database
ISI
SICI code
1520-6106(20011129)105:47<11710:EMAOTT>2.0.ZU;2-R
Abstract
The article presents studies on the Taylor transport in disordered systems. We assume that a moving particle can exist in different states and that fo r each state its transport properties are described by a different linear e volution operator. The transition from one state to another is described by a Markov process in continuous time. The transition rates of the Markov pr ocess depend on a set of variable parameters that are randomly selected fro m a known probability density. This type of transport model is of interest in connection with the study of multiphasic transport, for example, in the case of chromatographic separation, neutron migration in nuclear reactions, or neutrino flow in astrophysical problems. We consider two different type s of effective medium approximations: (1) a global approach, which consists , of solving the Taylor problem for a given set of values of the of the ran dom parameters, followed by averaging the result, and (2) a local approach. for which the averaging is done for small macroscopic regions of the syste m, which leads to a system of age-dependent master equations. We show that the averaging in the global approach induces an artificial collective behav ior that results in ballistic diffusion. The local approach may lead either to normal or dispersive transport. We apply our theory to the experiment o f Drazer and Zanette (Phys. Rev. E. 1999, 60, 5858) and show that that the local approach is in agreement with experimental data.