T. Piotrowski et al., Effect of the symmetry of the calix[4]pyrrole cavity on sensitivity and selectivity of potentiometric sensors for neutral nitrophenols, MAT SCI E C, 18(1-2), 2001, pp. 223-228
Lipophilic macrocyclic and acyclic derivatives of pyrrole were applied as s
ensory elements of liquid membrane potentiometric sensors destined for the
recognition of neutral forms of nitrophenol isomers. All compounds displaye
d high ability for the uptake of protons. The potential of liquid membranes
, containing pyrrole derivatives, strongly depended on the pH of the aqueou
s phase. Their potentiometric responses generated in the presence of nitrop
henol derivatives were investigated at three different pH: 4.0, 6.0 and 8.0
. All membranes investigated responded towards the neutral form of nitrophe
nol isomers. They did not respond to their anionic forms. The symmetry of t
he macrocyclic cavity of calix[4]pyrroles had a very mild effect on the mol
ecular recognition of nitrophenol guests. The membranes incorporating macro
cyclic pyrrole derivatives generated a higher potentiometric signal in the
presence of neutral nitrophenols in comparison to membranes containing acyc
lic pyrrole derivatives.
The sensors presented displayed high selectivity for para-nitrophenol. (C)
2001 Elsevier Science B.V. All rights reserved.