Accurate measurement of the helical twisting power of chiral dopants

Citation
T. Kosa et al., Accurate measurement of the helical twisting power of chiral dopants, MOLEC CRYST, 369, 2001, pp. 129-137
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
369
Year of publication
2001
Pages
129 - 137
Database
ISI
SICI code
Abstract
we report on an accurate measurement of the helical twisting power (HTP) of chiral dopants. In the usual Cano-wedge method, the wedge angle is determi ned from the separation of laser beams reflected from the windows of the te st cell. Here we propose to use an optical fiber based spectrometer to accu rately measure the call thickness instead. Knowing the cell thickness at th e positions of the disclination lines allows evaluation of the HTP. We show that this extension of the Cano-wedge method greatly increases the accurac y with which the HTP is determined.