CYTOCHROME-P-450 MODEL REACTIONS .3. ISOLATION AND CHARACTERIZATION OF A PORPHINATOMANGANESE(IV) COMPLEX FROM THE REACTION OF DICHLORO MONOXIDE WITH RAKIS-(2,6-DICHLOROPHENYL)PORPHINATOMANGANESE(III) CHLORIDE [MN(TDCPP)CL]

Authors
VOLZ H MULLER W
Citation
H. Volz et W. Muller, CYTOCHROME-P-450 MODEL REACTIONS .3. ISOLATION AND CHARACTERIZATION OF A PORPHINATOMANGANESE(IV) COMPLEX FROM THE REACTION OF DICHLORO MONOXIDE WITH RAKIS-(2,6-DICHLOROPHENYL)PORPHINATOMANGANESE(III) CHLORIDE [MN(TDCPP)CL], Chemische Berichte, 130(8), 1997, pp. 1099-1103
Citations number
62
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
130
Issue
8
Year of publication
1997
Pages
1099 - 1103
Database
ISI
SICI code
0009-2940(1997)130:8<1099:CMR.IA>2.0.ZU;2-Q
Abstract
The isolation at -78 degrees C and characterization of the novel cryst alline reactive porphinatomanganese(IV) complex Mn(TDCPP)(OCl)(2) (5) is described. 5 is compared with the porphinatomanganese(IV) complexes Mn(TDCPP)(C6H5IOCl)(2) (2), Mn(TDCPP)(C6F5IOCl)Cl (3) and Mn(TDCPP)(O CH3)(2) (4). The stoichiometric reaction of 5 with triphenylphoshane y ields 2.5 equivalents of triphenylphosphane oxide and 1.0 equivalent o f Mn(TDCPP)Cl (1). Complex 5 epoxidizes stilbene, and oxygenates and c hlorinates cyclohexane.