Hydroamination of alkynes catalyzed by a titanium pyrrolyl complex

Authors
Cao, CS Ciszewski, JT Odom, AL
Citation
Cs. Cao et al., Hydroamination of alkynes catalyzed by a titanium pyrrolyl complex, ORGANOMETAL, 20(24), 2001, pp. 5011-5013
Citations number
44
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
24
Year of publication
2001
Pages
5011 - 5013
Database
ISI
SICI code
0276-7333(20011126)20:24<5011:HOACBA>2.0.ZU;2-B
Abstract
The readily prepared pyrrolyl complex Ti(NMe2)(2)(dpma), where dpma is di(p yrrolyl-alpha -methyl)methylamine, is an effective precatalyst for the hydr oamination of alkynes by primary amines. The catalysis is Markovnikov-selec tive and rapid with terminal alkynes.