Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

Authors
Garner, M Lehmann, MA Reglinski, J Spicer, MD
Citation
M. Garner et al., Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls, ORGANOMETAL, 20(24), 2001, pp. 5233-5236
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
24
Year of publication
2001
Pages
5233 - 5236
Database
ISI
SICI code
0276-7333(20011126)20:24<5233:S(SCOM>2.0.ZU;2-Z
Abstract
The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten comple xes with hydrotris(methimazolyl)borate (Tm) are reported as the first examp les of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexe s. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexe s, leading to predictions regarding their reactions.