Platinum stannaborate complexes: Activated isonitrile insertion

Authors
Marx, T Pantenburg, I Wesemann, L
Citation
T. Marx et al., Platinum stannaborate complexes: Activated isonitrile insertion, ORGANOMETAL, 20(24), 2001, pp. 5241-5244
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
24
Year of publication
2001
Pages
5241 - 5244
Database
ISI
SICI code
0276-7333(20011126)20:24<5241:PSCAII>2.0.ZU;2-R
Abstract
The stannaborate complexes (Ph3P)(H11B11Sn)Pt(tBuNC)[C(Ph)NHtBu]} (2) and { (ddpe)(H11B11Sn)Pt[C(Ph)NHtBu]} (4) were obtained by insertion of tBuNC int o the Pt-Ph bond of [Bu3MeN][trans-(Ph3P)(2)Pt(Ph)(SnB11H11)] and [Bu3MeN][ (dppe)Pt(Ph)(SnB11H11)] at room temperature. The insertion products were ch aracterized by elemental analysis, NMR spectroscopy, and X-ray crystal stru cture analysis.