Membrane voltammetry: The interface between two immiscible electrolyte solutions

Authors
Kralj, B Dryfe, RAW
Citation
B. Kralj et Raw. Dryfe, Membrane voltammetry: The interface between two immiscible electrolyte solutions, PHYS CHEM P, 3(23), 2001, pp. 5274-5282
Citations number
59
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
3
Issue
23
Year of publication
2001
Pages
5274 - 5282
Database
ISI
SICI code
1463-9076(2001)3:23<5274:MVTIBT>2.0.ZU;2-E
Abstract
The voltammetric response obtained when the interface between two immiscibl e electrolyte solutions (ITIES) is modified by commercially available, trac k-etched membrane materials is reported. The electrochemical response is co nsistent with the location of the ITIES within the pores of the membrane ma terial, i.e. ensembles of micro-ITIES are generated by this procedure. The mass-transport phenomena peculiar to these types of interface and prospects for the measurement of interfacial kinetics are discussed.