We provide evidence for the temperature-induced metallization (TIM) of Si(1
00) surface. A TIM takes place at about 600 K without any change in surface
periodicity. Contrary to previous suggestions, photoemission spectroscopy
(PES) reveals that the TIM is not related to the (instantaneous) symmetriza
tion of asymmetric dimers. We suggest that Si adatoms produced at elevated
temperatures play a role of donor, giving rise to the TIM.