Two-dimensional vector fields undergoing a Hopf bifurcation are studied in
a Liouville-equation approach, The Liouville equation rules the time evolut
ion of statistical ensembles of trajectories issued from random initial con
ditions. but evolving under the deterministic dynamics. The time evolution
of the probability densities of such statistical ensembles can be decompose
d in terms of the spectrum of the resonances (i.e., the relaxation rates) o
f the Liouvillian operator or the related Frobenius-Perron operator. The sp
ectral decomposition of the Liouvillian operator is explicitly constructed
before, at, and after the Hopf bifurcation. Because of the emergence of tim
e oscillations near the Hopf bifurcation, the resonance spectrum turns out
to be complex and defined by both relaxation rates and oscillation frequenc
ies. The resonance spectrum is discrete far from the bifurcation and become
s continuous at the bifurcation. This continuous spectrum is caused by the
critical slowing down of the oscillations occurring at the Hopf bifurcation
and it leads to power-law relaxation as 1/roott of the probability densiti
es and statistical averages at long times t-->infinity. Moreover. degenerac
y in the resonance spectrum is shown to yield a Jordan-block structure in t
he spectral decomposition.