Processing and properties of polymeric nano-composites

Citation
H. Wang et al., Processing and properties of polymeric nano-composites, POLYM ENG S, 41(11), 2001, pp. 2036-2046
Citations number
19
Categorie Soggetti
Material Science & Engineering
Journal title
POLYMER ENGINEERING AND SCIENCE
ISSN journal
00323888 → ACNP
Volume
41
Issue
11
Year of publication
2001
Pages
2036 - 2046
Database
ISI
SICI code
0032-3888(200111)41:11<2036:PAPOPN>2.0.ZU;2-8
Abstract
Polymeric nano-composites are prepared by melt intercalation in this study. Nano-clay is mixed with either a polymer or a polymer blend by twin-screw extrusion. The clay-spacing in the composites is measured by X-ray diffract ion (XRD). The morphology of the composites and its development during the extrusion process are observed by scanning electron microscopy (SEM). Melt viscosity and mechanical properties of the composites and the blends are al so measured. It Is found that the clay spacing in the composites is influen ced greatly by the type of polymer used. The addition of the nano-clay can greatly increase the viscosity of the polymer when there is a strong inter- action between the polymer and the nano-clay. It can also change the morpho logy and morphology development of nylon 6/PP blends. The mechanical test s hows that the presence of 5-10 wt.% nano-clay largely increases the elastic modulus of the composites and blends, while significantly decreases the im pact strength. The water absorption of nylon 6 is decreased with the presen ce of nano-clay. The effect of nano-clay on polymers and polymer blends is also compared with Kaolin clay under the same experimental conditions.