Aluminium-SALEM complex: a new catalyst for the enantioselective Michael reaction

Authors
Citation
Sc. Jha et Nn. Joshi, Aluminium-SALEM complex: a new catalyst for the enantioselective Michael reaction, TETRAHEDR-A, 12(17), 2001, pp. 2463-2466
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
17
Year of publication
2001
Pages
2463 - 2466
Database
ISI
SICI code
0957-4166(20010928)12:17<2463:ACANCF>2.0.ZU;2-8
Abstract
A new heterobimetallic complex prepared from a chiral SALEM ligand and Red- Al-(R) was found to catalyse the Michael reaction between various dialkyl m alonates and cycloalkenones to give products in high yields with e.e.s of u p to 58%. (C) 2001 Elsevier Science Ltd. All rights reserved.