[1,5-Bis(1-methyl-1H-tetrazol-5-yl-kappa N)-3-oxopentane-kappa O]dichlorocopper(II)

Citation
As. Lyakhov et al., [1,5-Bis(1-methyl-1H-tetrazol-5-yl-kappa N)-3-oxopentane-kappa O]dichlorocopper(II), ACT CRYST C, 57, 2001, pp. 1374-1375
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
12
Pages
1374 - 1375
Database
ISI
SICI code
0108-2701(200112)57:<1374:[NO>2.0.ZU;2-E
Abstract
The title compound, [CuCl2(C8H14N8O)], is the rrst structurally characteriz ed molecular chelate complex of a binuclear N-substituted tetrazole. The Cu atom is five-coordinate, with an approximately square-pyramidal geometry. The equatorial positions of the pyramid are occupied by two Cl atoms and tw o N atoms from the ligand molecule; the O atom of the ligand lies in the ax ial position. Each complex is connected to four others via weak C-H . . . C l and C-H . . .N interactions, forming sheets parallel to the (010) plane.