cis-Dichlorobis(triethylarsine)platinum(II) and cis-dichlorobis(triethylphosphine)platinum(II)

Authors
Otto, S Muller, AJ
Citation
S. Otto et Aj. Muller, cis-Dichlorobis(triethylarsine)platinum(II) and cis-dichlorobis(triethylphosphine)platinum(II), ACT CRYST C, 57, 2001, pp. 1405-1407
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
12
Pages
1405 - 1407
Database
ISI
SICI code
0108-2701(200112)57:<1405:CAC>2.0.ZU;2-S
Abstract
The crystal structure of cis-[PtCl2(C6H15As)(2)], (I), is isostructural wit h a previously reported structure of cis-[PtCl2-(C6H15P)(2)],(II). A new po lymorph of (II) is also reported here. Selected geometrical parameters in t he arsine complex are Pt-Cl 2.3412 (12) and 2.3498 (13), Pt-As 2.3563 (6) a nd 2.3630 (6) Angstrom, Cl-Pt-Cl 88.74 (5), As-Pt-As 97.85 (2), and Cl-Pt-A s 171.37 (4) and 177.45 (4)degrees. Corresponding parameters in the phosphi ne complex are Pt-Cl 2.364 (2) and 2.374 (2), Pt-P 2.264 (2) and 2.262 (2) Angstrom, Cl-Pt-Cl 85.66 (9), P-Pt-P 98.39 (7), and Cl-Pt-P 170.26 (7) and 176.82 (8)degrees.