Tetrabenzo-24-crown-8 tris(1,2-dichloroethane) solvate

Authors
Bryan, JC Levitskaia, TG
Citation
Jc. Bryan et Tg. Levitskaia, Tetrabenzo-24-crown-8 tris(1,2-dichloroethane) solvate, ACT CRYST C, 57, 2001, pp. 1457-1459
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
12
Pages
1457 - 1459
Database
ISI
SICI code
0108-2701(200112)57:<1457:TTS>2.0.ZU;2-A
Abstract
The title compound, C32H32O8. 3C(2)H(4)Cl(2), illustrates how tetrabenzo-24 -crown-8 may be solvated by a common solvent-extraction diluent, 1,2-dichlo roethane (DCE). Two molecules of DCE occupy the crown cavity, forming weak hydrogen bonds to the ether O atoms and the crown arene rings, while the cr own adopts its most commonly observed binding conformation. The asymmetric unit is composed of two molecules of tetrabenzo-24-crown-8 and six molecule s of DCE.