Continuous wavelet transform and its application to resolving and quantifying the overlapped voltammetric peaks

Citation
L. Nie et al., Continuous wavelet transform and its application to resolving and quantifying the overlapped voltammetric peaks, ANALYT CHIM, 450(1-2), 2001, pp. 185-192
Citations number
20
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICA CHIMICA ACTA
ISSN journal
00032670 → ACNP
Volume
450
Issue
1-2
Year of publication
2001
Pages
185 - 192
Database
ISI
SICI code
0003-2670(200112)450:1-2<185:CWTAIA>2.0.ZU;2-K
Abstract
In order to resolve and quantify the overlapped peaks of voltammetry that c an be described by sech(2)-function, continuous wavelet transform (CWT) is employed. Through CWT by using Marr wavelet, qualitative and quantitative a nalysis for the mixed solution of Cd(II) and In(III) can be performed from unresolved square wave voltammogram (SWV) and relevant theoretical basis is provided. A new method to construct the baseline for quantitative determin ation is also proposed. The results of analysis indicate that the overlappe d voltammogram can be resolved and quantified effectively, conveniently and satisfactorily via CWT. (C) 2001 Elsevier Science B.V All rights reserved.