Trigonal-bipyramidal geometry in a cobalt(II) complex with an unsymmetrical tripodal ligand

Authors
Lim, JW Mikuriya, M Sakiyama, H
Citation
Jw. Lim et al., Trigonal-bipyramidal geometry in a cobalt(II) complex with an unsymmetrical tripodal ligand, B CHEM S J, 74(11), 2001, pp. 2131-2132
Citations number
6
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
74
Issue
11
Year of publication
2001
Pages
2131 - 2132
Database
ISI
SICI code
0009-2673(200111)74:11<2131:TGIACC>2.0.ZU;2-V
Abstract
yA cobalt(II) complex with bis[2-(3,5-dimethylpyrazol-1-yl)ethyl][(pyrazol- 1-yl)methyl]amine (bppa), [CoCl(bppa)][B(C6H5)(4)].C2H5OH, was synthesized and characterized by measurements of the magnetic moment and the electronic spectra. The X-ray crystal structure shows that the compound has a distort ed trigonal bipyramid with a N4Cl coordination environment.