Charge distribution within 1,2-dicarba-closo-dodecaborane: Dipole moments of its phenyl derivatives

Citation
D. Hnyk et al., Charge distribution within 1,2-dicarba-closo-dodecaborane: Dipole moments of its phenyl derivatives, COLL CZECH, 66(9), 2001, pp. 1375-1379
Citations number
19
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
66
Issue
9
Year of publication
2001
Pages
1375 - 1379
Database
ISI
SICI code
0010-0765(200109)66:9<1375:CDW1DM>2.0.ZU;2-D
Abstract
The dipole moment of 1,2-dicarba-closo-dodecaborane is oriented with the po sitive end towards the carbon atoms as follows from measurements on phenyl derivatives with variable substituents. Towards the phenyl group, the subst ituent 1,2-C2B10H11 behaves as a weak electron acceptor.