Magnetic properties of crystals of the molecular complex between fullereneC60 and an organic donor 9,9(')-trans-bis(telluraxanthenyl)

The EPR and static magnetic susceptibility of the crystalline molecular com plex between fullerene C60 and an organic donor 9,9(')-trans-Bis(telluraxan thenyl) (BTX) have been measured as functions of temperature. At temperatur es T above 130 K, the samples exhibit anomalously high magnetic susceptibil ity exceeding the values calculated under the assumption that each molecule bears one paramagnetic spin 1/2. A very intense magnetic resonance signal is also observed in the samples in the region of high g factors (g > 4.5). This allows the suggestion that the samples under study possess ferromagnet ism (or superparamagnetism). The EPR signal and magnetic susceptibility sha rply decay almost to zero as the temperature decreases below 100-120 K. It is supposed that electron transfer from donor molecules BTX to C60 molecule s takes place at temperatures above 110 K. This electron transfer generates electron spins in the system, whereas the anomalously high magnetism is du e to ferromagnetic correlations in the system of these spins. (C) 2001 MAIK "Nauka/Interperiodica".