Synthesis of graft copolymeric membranes of poly(vinyl alcohol) and polyacrylamide for the pervaporation separation of water/acetic acid mixtures

Graft copolymers of poly(vinyl alcohol) (PVA) with polyacrylamide were prep ared and membranes were fabricated at 48 and 93% grafting of acrylamide ont o PVA. These membranes were used in the pervaporation separation of water/a cetic acid mixtures at 25, 35, and 45 degreesC. The permeation flux, separa tion selectivity, diffusion coefficient, and permeate concentration were de termined. The highest separation selectivity of 23 for neat PVA at 25 degre esC and the lowest value of 2.2 for 93% acrylamide-grafted PVA membranes we re observed. A permeation flux of 1.94 kg m(-2) h(-1) was found for the 93% grafted membrane at 90 mass % of water in the feed mixture. The diffusion coefficients in a water/acetic acid mixture had an effect on the membrane p ermselectivity. The Arrhenius equation was used to calculate the activation parameters for permeation as well as for the diffusion of water and of ace tic acid. The activation energy values for the permeation flux varied from 97 to 28 kJ/mol. (C) 2002 John Wiley & Sons, Inc.