The fretting wear of sulphur-deficient MOSx coatings with different crystal
lographic orientations has been investigated in ambient air of controlled r
elative humidity. The coefficient of friction and the wear rate of MoSx coa
tings sliding against corundum depend not only on fretting parameters like
contact stress, fretting frequency, and relative humidity, but also strongl
y on the crystallographic orientation of the coatings. For randomly oriente
d MoSx coatings, the coefficient of friction and the wear rate increased si
gnificantly with increasing relative humidity. In contrast, basal-oriented
MOSx coatings were less sensitive to relative humidity. The coefficient of
friction of both types of MoSx coatings decreased on sliding against corund
um with increasing contact stress and decreasing fretting frequency. A corr
elation between dissipated energy and wear volume is proposed. This approac
h allows detection in a simple way of differences in fretting wear resistan
ce between random- and basal-oriented MoSx coatings tested in ambient air o
f different relative humidity.