The tridurylsilylium and tridurylstannylium cations: Free and not so free

Authors
Lambert, JB Lin, LJ
Citation
Jb. Lambert et Lj. Lin, The tridurylsilylium and tridurylstannylium cations: Free and not so free, J ORG CHEM, 66(25), 2001, pp. 8537-8539
Citations number
11
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
66
Issue
25
Year of publication
2001
Pages
8537 - 8539
Database
ISI
SICI code
0022-3263(200112)66:25<8537:TTATCF>2.0.ZU;2-P
Abstract
Allyltridurylsilane has been prepared and converted to the tridurylsilylium cation by treatment with electrophiles. Allyltridurylstannane has been pre pared and converted to the tridurylstannylium cation under similar conditio ns. The Si-29 chemical shift of the silylium cation indicates that it is fr ee and tricoordinate, whereas the Sn-119 chemical shift of the stannylium c ation indicates that it maintains loose fourth coordination with the solven t or the anion.