Organometallic building blocks for crystal engineering. Synthesis, structure and hydrogen bonding interactions in [Fe(eta(5)-C5H4-CH2(CH3)OH)(2)], [Fe(eta(5)-C5H3(CH3)COOH)(2)], [Fe(eta(5)-C5H4CH(CH3)NH(eta(5)-C5H4CH(CH3))] and in the diaminecyclohexane salt [Fe(eta(5)-C5H4COO)(2)](2-) [(1S,2S)-(NH3)(2)C6H10](2+)center dot 2[H2O]

Authors
Braga, D Maini, L Paganelli, F Tagliavini, E Casolari, S Grepioni, F
Citation
D. Braga et al., Organometallic building blocks for crystal engineering. Synthesis, structure and hydrogen bonding interactions in [Fe(eta(5)-C5H4-CH2(CH3)OH)(2)], [Fe(eta(5)-C5H3(CH3)COOH)(2)], [Fe(eta(5)-C5H4CH(CH3)NH(eta(5)-C5H4CH(CH3))] and in the diaminecyclohexane salt [Fe(eta(5)-C5H4COO)(2)](2-) [(1S,2S)-(NH3)(2)C6H10](2+)center dot 2[H2O], J ORGMET CH, 637, 2001, pp. 609-615
Citations number
47
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
637
Year of publication
2001
Pages
609 - 615
Database
ISI
SICI code
0022-328X(200112)637:<609:OBBFCE>2.0.ZU;2-A
Abstract
The novel ferrocene-based compounds [Fe(eta (5)-C5H4-CH(CH3)OH)(2)] (1), [F e(eta (5)-C5H3(CH3)COOH)(2)] (2), [Fe(eta (5)-C5H4CH-(CH3)NH(eta (5)-C5H4CH (CH3))] (3) and the diaminecyclohexane salt [Fe(eta (5)-C5H4 COO)(2)](2-) [ 1S,2S-(NH3)(2)C6H10](2+) .2[H2O] (4) have been synthesised and their molecu lar and supramolecular structures determined by single-crystal X-ray diffra ction. The hydrogen bonding networks established by the -COOH, CH(CH3)OH, a nd -COO(-) groups have been studied and the structural parameters compared with those available for the prototypical dicarboxylic acid [Fe(eta (5)-C5H 4COOH)(2)]. (C) 2001 Elsevier Science B.V. All rights reserved.