Ferrocene derivatives (I). Synthesis and X-ray structure determination of N-o-methylphenylferrocenesulfonamide

Authors
Li, M Bai, YJ Lu, J Yang, BQ Zhu, KK Ma, HR
Citation
M. Li et al., Ferrocene derivatives (I). Synthesis and X-ray structure determination of N-o-methylphenylferrocenesulfonamide, J ORGMET CH, 637, 2001, pp. 738-741
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
637
Year of publication
2001
Pages
738 - 741
Database
ISI
SICI code
0022-328X(200112)637:<738:FD(SAX>2.0.ZU;2-X
Abstract
N-o-Methylphenylferrocenesulfonamide was synthesized from the reaction of f errocenesulfonyl chloride with o-toluidine. The structure was determined by single-crystal diffraction. Crystal data: monoclinic, P2(1)/c, with unit c ell dimensions of a = 10.436(2), b = 12.377(3) c = 12.6431(3) Angstrom, and beta = 107.42(1)degrees, V = 1558.1(6) Angstrom (3), Z = 4. The most stabl e structure of the complex in theory was obtained by the Hartree-Fock SCF O f GAUSSIAN 98W, and the two results have been compared. (C) 2001 Elsevier S cience B.V. All rights reserved.