Reactivity of the bis(allyl)-ruthenium(IV) dimer [{Ru(eta(3):eta(3)-C10H16)(mu-Cl)Cl}(2)] (C10H16=2,7-dimethylocta-2,6-diene-1,8-diyl) towards dppf (dppf = [Fe(eta(5)-C5H4PPh2)(2)]) and dppfO (dppfO = [Fe(eta(5)-C5H4PPh2)(eta(5)-C5H4P(=O)Ph-2)])

Authors
Cadierno, V Garcia-Garrido, SE Gimeno, J
Citation
V. Cadierno et al., Reactivity of the bis(allyl)-ruthenium(IV) dimer [{Ru(eta(3):eta(3)-C10H16)(mu-Cl)Cl}(2)] (C10H16=2,7-dimethylocta-2,6-diene-1,8-diyl) towards dppf (dppf = [Fe(eta(5)-C5H4PPh2)(2)]) and dppfO (dppfO = [Fe(eta(5)-C5H4PPh2)(eta(5)-C5H4P(=O)Ph-2)]), J ORGMET CH, 637, 2001, pp. 767-771
Citations number
50
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
637
Year of publication
2001
Pages
767 - 771
Database
ISI
SICI code
0022-328X(200112)637:<767:ROTBD[>2.0.ZU;2-N
Abstract
The bis(allyl)-ruthenium(IV) derivative [ Ru(eta (3):eta (3)-C10H16)(mu -Cl )Cl}(2)] reacts with dppf and dppfO to yield complexes [{Ru(eta (3):eta (3) -C10H16)Cl-2}(2)(mu -dppf)] and [Ru(eta (3):eta (3)-C10H16) Cl-2(kappa (1)- P-dppfO)], respectively. The electrochemical data of these complexes are re ported. (C) 2001 Elsevier Science B.V. All rights reserved.