Citation
F. Tisato et al., Technetium and rhenium heterocomplexes containing the diphenylphosphinoferrocenyl fragment, J ORGMET CH, 637, 2001, pp. 772-776
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X
→ ACNP
Volume
637
Year of publication
2001
Pages
772 - 776
Database
ISI
SICI code
0022-328X(200112)637:<772:TARHCT>2.0.ZU;2-0
Abstract
Reactions of dppf with labile technetium. and rhenium precursors such as [M
(N)CI4](-) and [M(NPh)Cl-3(PPh3)(2)] yield the monomeric mono-substituted [
M(N)Cl-2(dppf)] and [M(NPh)Cl-3(dppf)] complexes, where the diphosphinoferr
ocenyl fragment coordinates on the equatorial plane of a distorted square p
yramid or of a distorted octahedron, respectively. (C) 2001 Elsevier Scienc
e B.V. All rights reserved.