Dehydrogenation reaction from a dihydrogen bonded precursor complex in thegas phase

Authors
Patwari, GN Ebata, T Mikami, N
Citation
Gn. Patwari et al., Dehydrogenation reaction from a dihydrogen bonded precursor complex in thegas phase, J PHYS CH A, 105(48), 2001, pp. 10753-10758
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY A
ISSN journal
10895639 → ACNP
Volume
105
Issue
48
Year of publication
2001
Pages
10753 - 10758
Database
ISI
SICI code
1089-5639(200112)105:48<10753:DRFADB>2.0.ZU;2-N
Abstract
In this paper, we present mass spectroscopic evidence for the dehydrogenati on reaction from a dihydrogen bonded complex between phenol and borane-trim ethylamine following resonance enhanced multiphoton ionization in the gas p hase. The evidence presented herein is based on observed fragmentation patt ern of the complex cation having high internal energy. To the best of our k nowledge, it is the first report of such observation.