Absolute total cross sections for electron-impact single ionization of Alq (q = 3-7) ions are investigated experimentally as well as theoretically. E
mploying the crossed-beams technique, the cross sections have been measured
from below the respective ground state threshold up to 1 keV and partly up
to 5.5 keV. The theoretical calculations were performed using the configur
ation-averaged distorted-wave method, including both direct ionization and
excitation-autoionization contributions from the 2p-shell. The measurements
are in good agreement with the calculations considering a small content of
metastable ions in the incident ion beam. Because of the strong dominance
by direct ionization processes the semiempirical Lotz formula can describe
the measured data as well.