Sc. Park et al., Effects of iron substitution for nickel on electrochemical properties of LiNi0.8Co0.2O2 for lithium rechargeable batteries, J POWER SOU, 102(1-2), 2001, pp. 130-134
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics","Environmental Engineering & Energy
iron was substituted for Ni in LiNi0.8Co0.2 in order to enhance its electro
chemical properties such as cycle life and rate capability. LiNi0.8-xFexCo0
.2O2 (0 less than or equal to x less than or equal to 0.1) wag synthesized
in flowing oxygen, for 12-48 h at 650-800 degreesC, and its structural and
electrochemical properties were characterized with X-ray diffraction (XRD),
cyclic voltammetry (CV) and charge-discharge tests. The XRD patterns of Li
Ni0.8-xFexCo0.2O2 showed that the alpha -NaFeO2 type layered structure was
maintained up to x = 0.1. As Fe was substituted for Ni up to x = 0.05, the
rate capability of LiNi0.8-xFexCo0.2O2 was improved. LiNi0.75Fe0.05Co0.2O2
showed better cycle stability than LiNi0.8Co0.2O2. XRD measurements indicat
ed that the lattice Of LiNi0.75Fe0.05Co0.2O2 expanded less than that of LiN
i0.8Co0.2O2 when the lithium was de-intercalated. CV curves of LiNi0.8-xFex
Co0.2O2 showed current peaks, which are related to the phase transitions, d
iminished with Fe substitution during charging and discharging owing to the
decrease of Ni3+. Consequently, the improved cycle stability of LiNi0.75Fe
0.05Co0.2O2 May be attributed to the decrease of phase transition. (C) 2001
Elsevier Science B.V. All rights reserved.